catena-Poly[cadmium(II)-μ-benzene-1,2-diamine-κ2 N:N′-di-μ-chlorido]
نویسندگان
چکیده
The title compound, [CdCl(2)(C(6)H(8)N(2))](n), is a coordination polymer prepared by the hydro-thermal reaction of cadmium chloride and o-diamino-benzene. The cadmium cation, located on an inversion center, is octa-hedrally coordinated by four Cl atoms at equatorial sites and two N atoms from two ligands at the axial sites. Cd atoms are bridged by Cl atoms, forming extended chains parallel to [010]. Neighboring chains are connected by N-H⋯Cl hydrogen bonds.
منابع مشابه
catena-Poly[[(8-aminoquinoline-κ2 N,N′)cadmium]-di-μ-thiocyanato-κ2 N:S;κ2 S:N-[(8-aminoquinoline-κ2 N,N′)cadmium]-di-μ-chlorido]
In the title compound, [CdCl(NCS)(C(9)H(8)N(2))](n), the Cd(II) atom is in a distorted octa-hedral coordination environment defined by two chloride anions, two N atoms from an 8-amino-quinoline ligand, one N atom from one thio-cyanate anion and one S atom from a symmetry-related thio-cyanate anion. Two Cd(II) atoms are bridged by two chloride anions, forming an inversion-related Cd(2)Cl(2) unit...
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